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hi cymro
i'm afraid your b is wrong

Thanks Chrise. I hadn’t parsed 22A but my solution fitted the last three words of the clue perfectly!

22 is an anagram with an extra letter

Yes, I’ve got that now but 24 D is still a mystery. I assume the definition is former homeland?

yes, it's another really obscure one. just follow the instructions and generate a very unlikely word!

Got it at last but this week had too many very obscure solutions.

Came here when I was about two-thirds done and stuck. Being made aware of the cunning gridfill helped a lot. However, there were a lot of very tricky obscurities which you can't really expect an average solver to know without recourse to aids.
Nevertheless, a very nice to look at final grid.