Wintonian - thank you very much for this thorough exposition; I'd already followed the path that you describe up until the solution of 6ac - but I then have the following difficulty:
At post #5 on this thread Xwordfan posted '6a in top left corner' - if this is correct (and as you say 'the answer to 6ac can go in only one position'); and if, also as you say '...the final digit of 6ac is......the same as the second digit of 7ac' , I cannot for the life of me see how any pentomino connecting the last digit in 6ac with the (identical) second digit in 7ac can possibly avoid putting the same digit in both first and second places in the two-digit down entry at top centre - which will then not be prime - so, wrong.
As you say:' the second digit of the two-digit entry at the top of the grid cannot be the same as the second digit of 7ac, or the entry would not be prime.'
The only explanation for this paradox that I can think of is that I've put 7ac in the wrong place - but I really can't see any alternative, and 3dn and 4dn seem to confirm its position.
As you and everyone else have solved this, I must be being extremely dense.
Any further comment? I've missed the post for submission, but don't want to just give up.