I'll try, 0pt0.
The 7th pairing is given by initial letters of the clues for 23d (an 'E') and 26d (an 'R') these code to the last two letters of the 3rd word of the thematic title (4th actually, but the first word has been discarded).
As one of these letters appears in both couplets all of these letters must appear in the same line (in this case a row, not a column). Because of the way letters in a line are encoded you know that the repeated letter should be in the middle of the other two.
The 5th pairing [9d & 10d with the two letters between the 1st and 2nd words of the theme title] contains all three letters of the 7th pairing plus one other letter (the additional letter must be at the far end of the same line because it codes to the letter at the start of the row).
Seeing these 5 letters in order should suggest a thematic word and completing it will contribute to the lines immediately above and below.