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Rod's inferior to Atlas from the neck down (4)

Atlas in mythology, condemned to hold up the sky/heavens for eternity.

Atlas is the name for the first (superior) vertebra of the neck.
Axis is the second (inferior) vertebra.

From the neck down means physically.

Letter from Greece has arsenic on envelope, impacting nerve centre (4)

A xi s
Arsenic affects nervous system.

Hub formed once Twitter ventures into cognitive computing. Musk's third! (4)

once Twitter = X inside cognitive computing = AI +S

Core erupts from Cotopaxi stratovolcano. (4)

It’s said the Axe is a confluence of the Exe and Wye (4)

As Chambers give axle as (obs) for axis, maybe #31 should be...

Elderly Rod's inferior to Atlas from the neck down (4)

1 vote each

Chrise @2
Jono @11
Buddy @12
SS @13
PaulH @25
Spike @31/36

also liked Geeker @3, Bacchanal @28

1 vote each to :
TYKE @ 6
JONO @ 11
BUDDY @ 12
GETING @ 22
PAULH @ 25
JONO @ 35

Top clues

1 - Jono@35
1 - Simplesimon@34
1 - Spikepunk@32
1- Paulh@25
1 - Buddy@12
1 - Aristo@19

1 each for...

Jono #11
Buddy #12
Ss #13
Aristo #19
Geting #24
Bacchanal #28