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Grahamr, thanks. Yes, Or as gold is more common, but it was good to learn something new anyway.

Yes, that painting was a piece of work... to solve.

Never heard of Poussin or the painting, only got it by Googling the name after I saw it mentioned here. Horribly obscure, seriously dreadful clue.

Which Poussin painting was it? There's one that's supposed to hold the secret of the Templar (or was it Cathar?) treasure, possibly solved by a local priest. (See various conspiracy books, including Holy blood and holy grail!

Et In Arcadia Ego, whatever that is.

Yes, that's the one - solve it and your fotune's made!
https://en.wikipedia.org/wiki/Et_in_Arcadia_ego

I gave this another go this morning, hoping coming to it afresh would help. It didn't. My wife said: 'You're obviously not enjoying it, why don't you do something else?' Sound advice.
I cheated to get the answers to a random few, which I still don't understand.

50d Had garden worker put up fences (5)
A: Owned.

47d Singer out of A&E – he's at home with us (6)
Briton.

54a Changing latest film in our name (2,3,4)
On the turn.

10d Heaven recalled in bible stories (7)
Nirvana.

50. Owned, had - upwards, put up, fences/contained inside.

47 Baritone, singer, with A and E removed, out of A and E.

10. Nirvana, heaven.
Ni = In recalled, backwards.
Ana = collection of stories
RV = Bible,

Ni rv ana.

54. Nth (latest) + ET (film) in OUR N

Thank you both, still don't understand 50d, where's the garden worker?