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19a Sign of rank cheese not quite acceptable (7)
Looks like ‘chevron’.

27a Architect by awful housing left country’s main city (9)
Nashville. I can see the construction but don’t understand the definition.

Nashville is country music's main city.... It's country as in style of music, not country as in a place.

Chèvre is goat’s cheese. On is acceptable, as in “not on”.

Thank you both.

2d Stripped chair cover from chatelaine's dwelling (9). The answer looks like residence, but I can't parse it?

(p)residen(t) c(hatelain)e