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25a Indefinite number - more than required - entering Kentucky is problematic (6), and 5d Speaker's prompt in announcing: "Reverse of alchemical process ending in failure (7). The answers look like Knotty and Autocue, but I can't parse them?

The reverse of alchemical process is Au to Cu (gold to copper).

Inside KY is n (indefinite #) + OTT (over the top)

Thanks, geeker.