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Another enjoyable puzzle from CheeseCracker spoiled for me because I'm unable to parse the wordplay of 15. From the crossers - T?I?MIN? - it can only be thiamine but I can't see the wordplay. Screeeeeaaaaam!
The clue, for total clarity is "Vitamin evident in bone following fracture".

thiamine is vitamin b1...b-one

Agreed Will37 an enjoyable but occasionally tricky puzzle
I have just 4d unsolved but will keep trying.

Jazzgirl, 4d is a variant spelling of what is defined by the last two words.

Thank you Jack. I have just checked and found in Chambers 12th

Many thanks, xwordfan. Goodness knows how much longer that might have eluded me.

Thanks to CheeseCracker. In Zulu time….😉

I’m just stuck on 33d. Have the test, and why, but missing this one. Punters would be good 😞

Can only follow the first part of your question ('test'? 'punters'?) so apologies if I'm missing something - the answer to 33d is 'teeth' ['tee' for support and the ends of t(oxtet)h].

It appears anna2424 is a newcomer, and has probably posted on the wrong thread.