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Teacher takes on York's top religious building (9)
?o???t?r? ( Not sure about the o)
About to request a barrel (4) ??s? (i think it must be cask but can't work out the C!)
Supporter provides the brain surgeon's first dodgy operation (7) ?r???e?
Thanks for help, I usually only have 2 to get at this stage but am having a bad crossword day!!!!!
Need the brain surgeons help!!!

Monastery ..... M(on)aster(y)

MONASTERY
Teacher - MASTER
takes ON Y(ork)

The letter c = circa (about)

Supporter provides the brain surgeon's first dodgy operation

B - brain surgeon's first + racket = bracket