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8D Popular pair of vitamins taken ? ? ? L ? ? ? E ?

14D Second and third bits of quartz crystal, perhaps S ? Y

16A Long answer from watchers in trouble ? ? C ?

thank you all

14 is SAY (perhaps)
S - second
third bits of quArtz crYstal

8, A C claimed ?

I think the other might be ITCH, but I can't parse it.

16, Itch. Anagram of "watchers in", minus "answer",

Well spotted, rusty