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Glad we could help, Whetstone. I didn't really like getting a pic of the clues and a pic of your half-completed grid - too much jumping around for me! I much prefer just helping out when the clues are given.

Ok fair enough.
6d. About to free up a Nobel Prize winner (5)
D_R--

Dirac, a Nobel winner in 1933!

Dir = Rid, free and

Ac = Ca, circa, about in Latin
Up - reversed, so Dir Ac.

25a. Coat replaced even before run (8)
-N-E---E

11. One of her best friends caught Lucrezia's heart (5)
C----

ENVELOPE
(even)* + lope (run)

Envelope

16d. Covering up, doctor to probe injury -prod heartily! (8)

-O---E-O

Must be an anagram in there.

11. Corgi. C + B(ORGI)A

16d Sombrero. MB in SORE + pROd