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A young woman might help ( with chaps around) (6) M?I?E?
Little islands, yet so unusual (5) E?O?S
Whatever Gustav's music was about, it was out if this world! (5) H?L??
Spare potassium will make the brain work (5) ??I?K

2 Eyots, kittle islands - anagram of 'yet so'.

4. Think, make brain work. Thin, spare +K,abbreviation for potassium.

Maiden
Eyots
Holst
Think

1 M aid en.

Maiden - Man around Aid

Eyots - Anag. Yet + So

Holst (the planets) - Gustav

Think - Thin (Spare) + K (Potassium)