Seem to be stuck on more clues than most of you other "forum-ers"(!)
5d. Work to bring to the surface old pigment ??H?E.
46a Everyone involved in in attempt to produce bit of salad S??ALL?
31d One goddess or another entertaining celebrity A?T?R?E
43d Huge figure, the number one, a queen T???N??
And one or two others ... but let's see if these help me.