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1d huge herbivorous dinosaur (11) a????o?????s
7a freezing lamp effectively
Freezing motion (11)
13a an improvement
(1,4,3,3,6)
6d science of heat and energy(14) t???????n???c?
31a process of making poor(14)
54a means of helping those
Who suffer from discrimination (11,6)
Help please , finding this week very difficult

13 A Turn For The Better
6 Thermodynamics?

6d thermodynamics

54 Affirmative Action?

I've put question marks as I never normally do the Times Two - I much prefer cryptic puzzles.

31 impoverishing?

1 ankylosaurus?

brontosaurus?

Glad we could help!

Impoverishing has only 13 letters l need 14 any ideas?

Impoverisation