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I know I should be able to work this 20 letter word out having got all of the alternate letters (hopefully!) The clue reads Polygonal structure provided by US money : church with more people and energy, not half

I have B-C-M-N-T-R-U-L-R-N-

CAN ANYONE PUT ME OUT OF MY MISERY?

Buckminsterfullerene

Buck + Minster + Fuller + Ene(rgy)

Wow!! thanks for that. I would never have got this in a thousand years.

You're welcome.