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Last two, any help much appreciated:

24a (4,5): The measure of a meteorologist to become angry, according to Spooner. I have r-i- / g-o-e
43d (7): Land borders in Greece opening routes up. I have s-r-g-l

Rain gauge? Gain rage by Spooner?

Senegal

Borders of GreecE : ge
In Routes : lanes ( reversed)

Borders of Greece - lanes - Senegal?

Thanks so much. Silly of me, I had thought of Senegal but for some reason, didn't get the parsing. Have a good weekend