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43a scientific test procedure (15) ????r?m???a????
39a one raising birds for shoot (10)
33d travelling around (11) p?????t?t?c
42d individually separate (8)
53a process of a substance changing into vapour (11)
.???o?a?i??
46d self inflicted punishment (7)

Any help please

Experimentation
Gamekeeper
Peripatetic
Discrete
Evaporation
Penance

43a experimentation
39a gamekeeper
33d peripatetic
42d discrete
53a evaporation
46d penance

Thanks very much jazzgirl

And Elle !

You're very welcome , Pammy!