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I will finish this on my own one day!

46 ac Tangle penetrating colonnades openings (7)
--o-a-a
46 dn Daughter's sitting around under the influence of drugs (7)
--d-t--
45 dn green goddess initially worried OLd Nick (7)
N-w-a--

46 Stomata (opening in plants) Mat (tangle) inside stoa (colonnade)

46 Stomata - it's 'mat' inside 'stoa' (pillars)
46 Sedated (d/daughter, inside 'seated')
45 Newgate - an old prison.

46d sedated. (d in seated)

thank you so much , got hung up on old nick being Satan