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Not done too badly on this one, but with sporadic problems still extant, so some assistance needed.

14A - Having split tea in chair, girl and boy rubbed up the wrong way (9)
I?R???TED
3D Cat, not large, accepted by old province's citizens (9)
N???O?A?S
26A - Truck starts to decelerate, slowly skirting London borough (8)
??A?I???
26D - Heartlessly declare intended challenge (8)
??F?A???
&
36D - First sign of Charlie Brown in uniform - as sort of comic strip? (11)
R?????G????

I hope that assistance with thes will help me do the other ones myself.

14 (cha) ir rita ted

26d defiance

3d nat (l)ion als

36d RECTANGULAR - regular=uniform, c(first of charlie) + tan (brown)

36d re-emergence ?

35d re c tan gular
26a d ealing s

26 Down is DEALINGS - the starts of D(ecelerate) and S(lowly) around the London Borough of EALING

36 Down is RECTANGULAR - first sign of C(harlie), brown is TAN inside REGULAR (= uniform)

ignore my post!

Many thanks to all who replied. However I never would ignore Jazzgirl despite her modesty.

26A is particularly galling - I was born in Ealing.

I'm now going to go away & wrestle with the remaining Ten.