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16a rubber-like latex
??t?e e?c?a
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Gutta-percha ?

Never heard of it! How is it used?

It's commonly used in golf balls

About 100 years ago, jazzy!

Oops!

Thank you ..... But what is used nowadays then?

There are a number of different types of construction, but the best have (I had better insert "I think") a liquid rubber core, wound around with lots of rubber tape, then finished with a resistant coating.

I learn a lot from this site!

33A. Frame on front of locomotive (10)

2D. Arouse a feeling of anticipation :(4,3,5,5)

Times 1024

2d: make the mouth water
33a: cowcatcher