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Stuck on two
25a Not qualified, so dismissed? Yes(8)
O?T?I?H?
4d Place outlined in perfect shade(6) P?R?L?

I can think of several answers but cannot see the reason so, please could you explain the reasoning? Thanks.

4d) purple pl=place perfect=pure

Outright? (not qualified) dismissed (out) + yes (right)

Thank you. Those were ones I was considering but was not convinced about. Will now deposit in the recycling!