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Stuck on several but these would help this wet evening:

5d "Agent is right about helium, say" (5,3)
?N??? GAS
21a "Orders fruit on island" (8) M?N???E?
20d "Pain gets to father if you do this visit"
(4-2)??O?-P?

inert gas.

21 mandates

drop in
take in, from pain, and you are left with Pa.

Thanks Trevor.

Drop-in -I don't think I would have got that even I had spelt Lipizzaner (the misplaced P)correctly!

Garwain

nice clue i thought (20d). not heard of a Lipizzaner before.