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Utterly stumped by 21ac and 19dn. Also confused by 11ac. Help!

Not easy to help out here until I know what the clues are!

21ac "set a course, perhaps, with divine surroundings"(7) s - e - e - -

19dn "Frame shy jockey consumed by resentment"(8) p - - - i - u -

11ac "Poet's rejected material"(5) t - i - e
Probably twine or thine but I have no idea why!

11a toile (Eliot reversed - t s eliot is the poet)

scenery
p hys ique

Thanks Sudokolover