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3.Not Jano, Marcho or even Mayo (4)
6.You could say she's handsome! (6,5)
22.Once inside, reluctant hero behaves (3,4)
25.In by oneself (4,5)
33.Madman! (6)
37.It's news! Spread it around (7)
40.US Helen of Troy(8,6)

40 another word for an inhabitant of USA + a stunner

25 Culkin came to fame here.

Thank you, now have them two.

2.Woman of the streets picked up by Richard Gere?

37. Mr H Ford investigates the Amish.

37. it's news (anag)

3. The daughter of Saturn and sister (but also the wife) of Jupiter.

22 I had red mélange.

6. 1964 Roy Orbison song.