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Last but not a clue.

25 across: Left at home, nurse tending (8)

Have: ?I?I?T?R

My guess the answer is minister but I cannot parse it and therefore am probably wrong.

Suggestions gratefully accepted.

Enigma

SINISTER (left)

SISTER around IN

Of course! Obvious now and that's why it's so infuriating. Thanks for your help.

Enigma