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any help much appreciated
1 dn Ancient Land in Lebanon and Syria (9)

19 ac Keeping in Good working condition (4,3,11)
3 down Largest landmass (7)
48 a Substance used in Chemistry (7)R*A*E**
thanks in advance

Eurasia
Reagent

48 reagent

19 care and maintenance?

Palestine

1 palestine

1d Phoenicia is the ancient land

I stand corrected Sudokulover !!..Phoenecia it is

and I cant spell it correctly!

Times 2,1 down is PHOENICIA,which relates to 5 down which is SYRIA, which relates to 45 down,which is PALMYRA.