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I also found this particularly difficult today.

Stuck on:
22 across. Eager one with speed of light entering event (7). i?c?ing
Answer, please.

Also, can you please tell me how to parse:

6a: excellent work after lean time. (3-3). I have top job, but I'm not sure.

Thanks!

itching - eager
c is speed of light
in
i (one) thing (event)

6a tip top - excellent
lean - tip
t (time) op (work)

Ah. Thanks cerasus. Tip top. of course. And I didn't know c was the speed of light.