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how about
22d. notable (esteemed didn't fit)
?S?E?I??
39a. assembling a group in order
M?R?????I?G (if webcam is right for the M)
35d. In a manner harmful to well being
U???U?T?I?Y
I am about to give up this week!

39 marshalling?

22d especial

35d unhealthily

Thank yo both so much. Noticed i had got a wrong letter in 35d it should read
U?H?A?T?I?Y

Clue was in a manner harmful to well being.

Jazzgirl and ChrisE ! You have saved my sanity today. Thank you so much to you both.